Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium

• Author(s): Dr. Arvind Prasad Dwivedi; Shweta Neeraj
• Paper ID: 1700793
• Page: 38-41
• Published Date: 22-11-2018
• Published In: Iconic Research And Engineering Journals
• Publisher: IRE Journals
• e-ISSN: 2456-8880
• Volume/Issue: Volume 2 Issue 5 November-2018

Abstract

The kinetics of reaction between aliphatic ℓ-amino acids and 1,3-dichloro-5,5-dimethylhydantoin have been studied in aqueous acetic acid medium yielding aliphatic aldehydes as the end-products by the ring cleavage oxidation. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity ℓ-amino acids (ℓ-Glycine > ℓ-Alanine) was explained on the basis of conformational considerations. A plausible mechanism and rate law supported by thermodynamic parameters was discussed.

Keywords

aliphatic aldehydes, demonstrates, reveals, plausible.

Citations

IRE Journals:
Dr. Arvind Prasad Dwivedi, Shweta Neeraj "Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium " Iconic Research And Engineering Journals Volume 2 Issue 5 2018 Page 38-41

IEEE:
Dr. Arvind Prasad Dwivedi, Shweta Neeraj "Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium " Iconic Research And Engineering Journals, vol. 2, no. 5, Nov. 2018

APA:
Dr. Arvind Prasad Dwivedi, Shweta Neeraj (2018). Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium . Iconic Research And Engineering Journals, 2(5).

MLA:
Dr. Arvind Prasad Dwivedi, Shweta Neeraj "Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium " Iconic Research And Engineering Journals, vol. 2, no. 5, Nov. 2018.

BibTeX

@article{1700793,
author = {Dr. Arvind Prasad Dwivedi, Shweta Neeraj},
title = {Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium },
journal = {Iconic Research And Engineering Journals},
year = {2018},
volume = {2},
number = {5},
pages = {38-41},
issn = {2456-8880},
url = {https://www.irejournals.com/formatedpaper/1700793.pdf},
abstract = {The kinetics of reaction between aliphatic ℓ-amino acids and 1,3-dichloro-5,5-dimethylhydantoin have been studied in aqueous acetic acid medium yielding aliphatic aldehydes as the end-products by the ring cleavage oxidation. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity ℓ-amino acids (ℓ-Glycine > ℓ-Alanine) was explained on the basis of conformational considerations. A plausible mechanism and rate law supported by thermodynamic parameters was discussed.},
keywords = {aliphatic aldehydes, demonstrates, reveals, plausible.},
month = {November}
}