Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium

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@article{1700793,
      author = {Dr. Arvind Prasad Dwivedi, Shweta Neeraj},
      title = {Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium },
      journal = {Iconic Research And Engineering Journals},
      year = {2018},
      volume = {2},
      number = {5},
      pages = {38-41},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1700793.pdf},
      abstract = {The kinetics of reaction between aliphatic ℓ-amino acids and 1,3-dichloro-5,5-dimethylhydantoin have been studied in aqueous acetic acid medium yielding aliphatic aldehydes as the end-products by the ring cleavage oxidation. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity ℓ-amino acids (ℓ-Glycine > ℓ-Alanine) was explained on the basis of conformational considerations. A plausible mechanism and rate law supported by thermodynamic parameters was discussed.},
      keywords = {aliphatic aldehydes, demonstrates, reveals, plausible.},
      month = {November},
  }