International Peer-Reviewed JournalOpen AccessISSN 2456-8880
irejournals@gmail.com+91-7433024337

Home / Current Issue / Paper 1701736

1701736 Vol 3 · Issue 5 Download Paper

Micro-Mechanics Mercerization Analysis On The Tensile Strength And Inter Phase Quality Of Stipa Stem Fiber-Reinforced Polypropylene Composite Materials

K. E. Madu E. I. Nwankwo G. O. Okoronkwo J. I. Onyewudiala

Subject area: Science,Engineering and Technology  ·  Area of research: Mechanical Engineering

Abstract

The Production of greener composite materials by substituting glass fibers with naturalfibers is a current field of research. If such natural fiber reinforcements come from agro-industrial side streams, as stipa stem fibers (SSFs) come from the extraction of stipa strands for the textile industry, an additional advantage can be identified. Nonetheless, such by-product fibers show some drawbacks, such as high lignin contents, which can make it difficult to obtain a good interphase between the fibers and the matrix and to obtain good fiber individualization. A digestion treatment at different NaOH contents is proposed to eliminate soluble lignin and extractives from the surface of the fibers. At the same time, the use of a coupling agent solves incompatibilities between the fibers and the matrix. The composites were tensile tested and the impact of the proposed treatments was evaluated and discussed. Later, the Kelly-Tyson modified equation and a modified rule of mixtures?the micro-mechanic models?were used to study the impact of such treatments on the quality of the interphase between the polymer and the reinforcement. Both treatments showed a high impact on the tensile strength and the quality of the interphase, obtaining competitive composite materials reinforced with SSFs derived from a by-product

Keywords

Stipa Fiber, Polypropylene, Tensile Strength, Bio-Composites, Micro - Mechanics, Mercerization, Interphase

References

[1] Anastas, P.T.;Warner, J. Green chemistry: Theory and practice; Oxford University Press: Oxford, UK, 1998.

[2] Barbera, L.; Pelach, M.A.; Perez, I.; Puig, J.; Mutje, P. Upgrading of hemp core for papermaking purposes by means of organosolv process. Ind. Crops Prod.2011, 34, 865–872. Polymers 2017, 9, 377 14 of 15

[3] Beg, M.D.H.; Pickering, K.L. reprocessing of wood fibre reinforced polypropylene composites. Part i: Effectson physical and mechanical properties. Compos Part A Appl. Sci. Manuf. 2008, 39, 1091–1100.

[4] Birnin-Yauri, A.; Ibrahim, N.; Zainuddin, N.; Abdan, K.; Then, Y.; Chieng, B. Effect of maleicanhydride-modified poly(lactic acid) on the properties of its hybrid fiber biocomposites. Polymers 2017,9, 165.

[5] Bledzki, A.K.; Franciszczak, P.; Osman, Z.; Elbadawi, M. Polypropylene biocomposites reinforced with softwood, abaca, jute, and kenaf fibers. Ind. Crops Prod.2015, 70, 91–99.

[6] Bowyer,W.H.; Bader, H.G. On the reinforcement of thermoplastics by imperfectly aligned discontinuous fibres. J. Mater. Sci. 1972, 7, 1315– 1321. Polymers 2017, 9, 377 15 of 15

[7] Delgado Aguilar, M.; Julián Pérez, F.; Pèlach Serra, M.À.; EspinachOrús, X.; Méndez González, J.A.; MutjéPujol, P. Fast and simple method for prediction of the micromechanical parameters and macro-mechanical properties of composite materials. Cellul. Chem. Technol. 2016, 50, 423–428.

[8] Delgado_Aguilar, M.; Julian, F.; Tarres, Q.; Mendez, J.A.; Mutje, P.; Espinach, F.X. Bio composite from bleached pine fibers reinforced polylactic acid as a replacement of glass fiber reinforced polypropylene, macro and micro- mechanics of the young’s modulus. Compos. Part B Eng. 2017, 125, 203–210.

[9] Dicker, M.P.M.; Duckworth, P.F.; Baker, A.B.; Francois, G.; Hazzard, M.K.;Weaver, P.M. Green composites: A review of material attributes and complementary applications. Compos. Part A Appl. Sci. Manuf. 2014, 56, 280–289.

[10] Espinach, F.X.; Granda, L.A.; Tarrés, Q.; Duran, J.; Fullana-i-Palmer, P.; Mutjé, P. Mechanical andmicromechanical tensile strength of eucalyptus bleached fibers reinforced polyoxymethylene composites.Compos. Part B Eng. 2017, 116, 333–339.

[11] Granda, L.A.; Espinach, F.X.; Lopez, F.; Garcia, J.C.; Delgado-Aguilar, M.; Mutje, P. Semi- chemical-fibres of leucaenacollinsii reinforced polypropylene: Macromechanical and micromechanical analysis. Compos. Part. B Eng. 2016, 91, 384–391.

[12] Hirsch, T. Modulus of elasticity of concrete affected by elastic moduli of cement paste matrix and aggregate.J. Am. Concr. Inst. 1962, 59, 427– 451.

[13] Kalaprasad, G.; Joseph, K.; Thomas, S.; Pavithran, C. Theoretical modelling of tensile properties of short sisalfibre-reinforced low- density polyethylene composites. J. Mater. Sci. 1997, 32, 4261–4267.

[14] Karmaker, A.C.; Youngquist, J.A. Injection molding of polypropylene reinforced with short jute fibers. J. Appl.Polym. Sci. 1996, 62, 1147– 1151.

[15] Kelly, A.; Tyson,W. Tensile porperties of fibre- reinforced metals - copper/tungsten and copper/molybdenum.J. Mech. Phys. Solids 1965, 13, 329–338.

[16] Koronis, G.; Silva, A.; Fontul, M. Green composites: A review of adequate materials for automotive applications. Compos. Part B Eng. 2013, 44, 120–127.

[17] La Rosa, A.D.; Cozzo, G.; Latteri, A.; Recca, A.; Bjorklund, A.; Parrinello, E.; Cicala, G. Life cycle assessment of a novel hybrid glass- hemp/thermoset composite. J. Cleaner Prod. 2013, 44, 69–76.

[18] Lopez, J.P.; Mendez, J.A.; El Mansouri, N.E.; Mutje, P.; Vilaseca, F. Mean intrinsic tensile properties of stonegroundwood fibers from softwood. BioResources2011, 6, 5037–5049.

[19] Lopez, J.P.; Mendez, J.A.; Espinach, F.X.; Julian, F.; Mutje, P.; Vilaseca, F. Tensile strength characteristics ofpolypropylene composites reinforced with stone groundwood fibers from softwood. BioResources2012, 7, 3188–3200.

[20] Lopez, J.P.; Vilaseca, F.; Barbera, L.; Bayer, R.J.; Pelach, M.A.; Mutje, P. Processing and properties ofbiodegradable composites based on Mater-Bi® and hemp core fibres. Resour. Conserv.Recycl.2012, 59, 38–42.

[21] Mendez, J.A.; Vilaseca, F.; Pelach, M.A.; Lopez, J.P.; Barbera, L.; Turon, X.; Girones, J.; Mutje, P. Evaluation of the reinforcing effect of ground wood pulp in the preparation of polypropylene- based composites coupled with maleic anhydride grafted polypropylene. J.Appl. Polym. Sci. 2007, 105, 3588–3596.

[22] Oliver-Ortega, H.; Granda, L.A.; Espinach, F.X.; Mendez, J.A.; Julian, F.; Mutjé, P. Tensile propertiesand micromechanical analysis of stone groundwood from softwood reinforced bio- based polyamide11composites. Compos. Sci. Technol. 2016, 132, 123–130.

[23] Pracella, M.; Haque, M.M.-U.; Alvarez, V. Functionalization, compatibilization and properties of polyolefincomposites with natural fibers. Polymers 2010, 2, 554.

[24] Reixach, R.; Espinach, F.X.; Arbat, G.; Julián, F.; Delgado-Aguilar, M.; Puig, J.; Mutjé, P. Tensile properties of polypropylene composites reinforced with mechanical, thermomechanical, and chemi-thermomechanical pulps from orange pruning. BioResources 2015, 10, 4544–4556.

[25] Reixach, R.; Espinach, F.X.; Franco-Marquès, E.; Ramirez de Cartagena, F.; Pellicer, N.; Tresserras, J.; Mutjé, P.Modeling of the tensile moduli of mechanical, thermomechanical, and chemi- thermomechanical pulps fromorange tree pruning. Polym.Compos.2013, 34, 1840–1846.

[26] Rivera-Gómez, C.; Galán-Marín, C.; Bradley, F. Analysis of the influence of the fiber type in polymer matrix/fiber bond using natural organic polymer stabilizer. Polymers 2014, 6,977.

[27] Sambale, A.; Schöneich, M.; Stommel, M. Influence of the processing parameters on the fiber-matrixinterphasein short glass fiber- reinforced thermoplastics. Polymers 2017, 9, 221.

[28] Serrano, A.; Espinach, F.X.; Tresserras, J.; del Rey, R.; Pellicer, N.; Mutje, P. Macro and micromechanics analysis of short fiber composites stiffness: The case of old newspaper fibers-polypropylene composites. Mater. Des. 2014, 55, 319–324.

[29] Shah, D.U.; Nag, R.K.; Clifford, M.J. Why do we observe significant differences between measured and 'back-calculated' properties of natural fibres? Cellulose 2016, 23, 1481–1490.

[30] Thomason, J.L. Interfacial strength in thermoplastic composites - at last an industry friendly measurement method? Compos. Part A Appl. Sci. Manuf. 2002, 33, 1283–1288.

[31] Vallejos, M.E.; Canigueral, N.; Mendez, J.A.; Vilaseca, F.; Corrales, F.; Lopez, A.; Mutje, P. Benefit from hemp straw as filler/reinforcement for composite materials. Afinidad2006, 63, 354– 361.

[32] Vallejos, M.E.; Espinach, F.X.; Julian, F.; Torres, L.; Vilaseca, F.; Mutje, P. Micromechanics of hemp strands in polypropylene composites. Compos.s Sci. Technol. 2012, 72, 1209– 1213.

[33] Vilaseca, F.; Valadez-Gonzalez, A.; Herrera- Franco, P.J.; Pelach, M.A.; Lopez, J.P.; Mutje, P. Biocompositesfrom abaca strands and polypropylene. Part i: Evaluation of the tensile properties. Bioresour. Technol. 2010,101, 387– 395.

How to cite this paper

K. E. Madu, E. I. Nwankwo, G. O. Okoronkwo, J. I. Onyewudiala "Micro-Mechanics Mercerization Analysis On The Tensile Strength And Inter Phase Quality Of Stipa Stem Fiber-Reinforced Polypropylene Composite Materials" Iconic Research And Engineering Journals Volume 3 Issue 5 2019 Page 73-88
K. E. Madu, E. I. Nwankwo, G. O. Okoronkwo, J. I. Onyewudiala "Micro-Mechanics Mercerization Analysis On The Tensile Strength And Inter Phase Quality Of Stipa Stem Fiber-Reinforced Polypropylene Composite Materials" Iconic Research And Engineering Journals, vol. 3, no. 5, Nov. 2019
K. E. Madu, E. I. Nwankwo, G. O. Okoronkwo, J. I. Onyewudiala (2019). Micro-Mechanics Mercerization Analysis On The Tensile Strength And Inter Phase Quality Of Stipa Stem Fiber-Reinforced Polypropylene Composite Materials. Iconic Research And Engineering Journals, 3(5).
K. E. Madu, E. I. Nwankwo, G. O. Okoronkwo, J. I. Onyewudiala "Micro-Mechanics Mercerization Analysis On The Tensile Strength And Inter Phase Quality Of Stipa Stem Fiber-Reinforced Polypropylene Composite Materials" Iconic Research And Engineering Journals, vol. 3, no. 5, Nov. 2019.
@article{1701736,
      author = {K. E. Madu, E. I. Nwankwo, G. O. Okoronkwo, J. I. Onyewudiala},
      title = {Micro-Mechanics Mercerization Analysis On The Tensile Strength And Inter Phase Quality Of Stipa Stem Fiber-Reinforced Polypropylene Composite Materials},
      journal = {Iconic Research And Engineering Journals},
      year = {2019},
      volume = {3},
      number = {5},
      pages = {73-88},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1701736.pdf},
      abstract = {The Production of greener composite materials by substituting glass fibers with naturalfibers is a current field of research. If such natural fiber reinforcements come from agro-industrial side streams, as stipa stem fibers (SSFs) come from the extraction of stipa strands for the textile industry, an additional advantage can be identified. Nonetheless, such by-product fibers show some drawbacks, such as high lignin contents, which can make it difficult to obtain a good interphase between the fibers and the matrix and to obtain good fiber individualization. A digestion treatment at different NaOH contents is proposed to eliminate soluble lignin and extractives from the surface of the fibers. At the same time, the use of a coupling agent solves incompatibilities between the fibers and the matrix. The composites were tensile tested and the impact of the proposed treatments was evaluated and discussed. Later, the Kelly-Tyson modified equation and a modified rule of mixtures?the micro-mechanic models?were used to study the impact of such treatments on the quality of the interphase between the polymer and the reinforcement. Both treatments showed a high impact on the tensile strength and the quality of the interphase, obtaining competitive composite materials reinforced with SSFs derived from a by-product},
      keywords = {Stipa Fiber, Polypropylene, Tensile Strength, Bio-Composites, Micro - Mechanics, Mercerization, Interphase},
      month = {November},
  }