Home / Current Issue / Paper 1705571
A Study on Synthesis of Helical Boron-Doped Polycyclic Aromatic Hydrocarbons (PAHs)
Subject area: Science,Engineering and Technology · Area of research: Polycyclic Aromatic Hydrocarbons
Abstract
The research article explores the innovative post-functionalization of doubly boron-doped polycyclic aromatic hydrocarbons (PAHs) through the introduction of various aryl substituents, specifically synthesizing a series of (2,8,)3,9-aryl-substituted 3,9-diboraperylenes via the boron-substitution of (2,8-diaryl-)3,9-dihydroxy-3,9-diboraperylenes, revealing that these newly synthesized boron-doped PAHs display two reversible reductions characterized by a notably facile first reduction potential ranging between E = ?1.04 and ?1.13 V versus Fc+/Fc, and additionally, the Friedel?Crafts cyclization of the 2-isopropenylnaphthyl-substituted derivative yields a helical boron-doped PAH, which exhibits advantageous properties including a low lowest unoccupied molecular orbital (LUMO) level, elevated absorption coefficients, and fluorescence with a quantum yield (?_F) of 0.73, coupled with the presence of a one-dimensional ??? stacking interaction in the solid state; furthermore, this study underscores the significance of structural modifications on the electronic characteristics and optical properties of boron-doped PAHs, thereby expanding the potential applications of such materials in fields like organic electronics and photonics
Keywords
Boron-Doped PAHs, Post-Functionalization, Aryl Substituents, Friedel?Crafts Cyclization, LUMO Level, Fluorescence Quantum Yield
How to cite this paper
@article{1705571,
author = {Dr. K. S. Lamani},
title = {A Study on Synthesis of Helical Boron-Doped Polycyclic Aromatic Hydrocarbons (PAHs)},
journal = {Iconic Research And Engineering Journals},
year = {2024},
volume = {7},
number = {9},
pages = {327-336},
issn = {2456-8880},
url = {https://www.irejournals.com/formatedpaper/1705571.pdf},
abstract = {The research article explores the innovative post-functionalization of doubly boron-doped polycyclic aromatic hydrocarbons (PAHs) through the introduction of various aryl substituents, specifically synthesizing a series of (2,8,)3,9-aryl-substituted 3,9-diboraperylenes via the boron-substitution of (2,8-diaryl-)3,9-dihydroxy-3,9-diboraperylenes, revealing that these newly synthesized boron-doped PAHs display two reversible reductions characterized by a notably facile first reduction potential ranging between E = ?1.04 and ?1.13 V versus Fc+/Fc, and additionally, the Friedel?Crafts cyclization of the 2-isopropenylnaphthyl-substituted derivative yields a helical boron-doped PAH, which exhibits advantageous properties including a low lowest unoccupied molecular orbital (LUMO) level, elevated absorption coefficients, and fluorescence with a quantum yield (?_F) of 0.73, coupled with the presence of a one-dimensional ??? stacking interaction in the solid state; furthermore, this study underscores the significance of structural modifications on the electronic characteristics and optical properties of boron-doped PAHs, thereby expanding the potential applications of such materials in fields like organic electronics and photonics},
keywords = {Boron-Doped PAHs, Post-Functionalization, Aryl Substituents, Friedel?Crafts Cyclization, LUMO Level, Fluorescence Quantum Yield},
month = {March},
}