Review on the Applications of Modified Chitosan as an Alternative Novel Materials for Chemical Technology

References

[1] S. N. Dalhatu et al., “L-Arginine Grafted Chitosan as Corrosion Inhibitor for Mild Steel Protection,” Polymers, vol. 15, no. 2, pp. 1–13, 2023. https://www.mdpi.com/2073- 4360/15/2/398

[2] E. P. F. Nhavene et al., “Chitosan grafted into mesoporous silica nanoparticles as benznidazol carrier for Chagas diseases treatment,” Microporous and Mesoporous Materials, vol. 272, no. June, pp. 265 –275, 2018. https:// 5

[3] B. Tsai, O. Garcia-Valdez, P. Champagne, and M. F. Cunningham, “Poly(poly(ethylene glycol) methyl ether methacrylate) grafted chitosan for dye removal from water,” Processes, vol. 5, no. 1, 2017.

[4] A. Manivel, S. Ramkumar, J. J. Wu, A. M. Asiri, and S. Anandan, “Journal of Environmental Chemical Engineering corrosion inhibitor for mild steel in acidic media,” vol. 2, pp. 463 –470, 2014. http://dx.

[5] C. Brasselet et al., “Modification of chitosan for the generation of functional derivatives,” Applied Sciences (Switzerland), vol. 9, no. 7, pp. 1–23, 2019. https://www.mdpi.com/2073- 4360/15/2/398

[6] L. S. Guinesi and É. T. G. Cavalheiro, “The use of DSC curves to determine the acetylation degree of chitin/chitosan samples,” Thermochimica Acta, vol. 444, no. 2, pp. 128– 133, 2006. https://

[7] S. N. Dalhatu, S. Khoonsap, S. Suwannarat, S. Amnuaypanich, and S. Amnuaypanich, “Biopolymer-based corrosion inhibitor from chitosan grafted with poly(2 - hydroxyethylmethacrylate) (CS-g-PHEMA) synthesized by ultrasound-assisted method,” Songklanakarin Journal of Science and Technology, vol. 44, no. 5, pp. 1225–1231, 2022.

[8] A. S. Fouda, F. I. El-Dossoki, and I. A. Shady, “Adsorption and corrosion inhibition behavior of polyethylene glycol on α-brass alloy in nitric acid solution,” Green Chemistry Letters and Reviews, vol. 11, no. 2, pp. 67–77, 2018. https://

[9] R. S. C. M. D. Q. Antonino et al., “Preparation and characterization of chitosan obtained from shells of shrimp (Litopenaeus vannamei Boone),” Marine Drugs, vol. 15, no. 5, pp. 1– 12, 2017. https://

[10] H. M. A. and R. M. Dalhatu sani Nazifi , Kolo Alhaji modu, Auwal Adamu Mahmoud, “Ultrasonic Assisted Synthesis and Characterization Of Chitosan Graf With 2- (dimethylaminoethylmethacrylate ) ( Dmaema ) Cs-G-Pdmaem,” Journal of Physical Sciences, vol. 3, no. 1, pp. 1 –10, 2021. https://www.researchgate.net/publication/35397 2318-

[11] T. B. Taketa et al., “Investigation of the Internal Chemical Composition of Chitosan-Based LbL Films by Depth-Profiling X-ray Photoelectron Spectroscopy (XPS) Analysis,” Langmuir, vol. 34, no. 4, pp. 1429–1440, 2018.

[12] E. V. R. Campos, J. L. Oliveira, and L. F. Fraceto, “Poly(ethylene glycol) and cyclodextrin-grafted chitosan: From methodologies to preparation and potential biotechnological applications,” Frontiers in Chemistry, vol. 5, no. NOV, pp. 1–15, 2017.

[13] I. O. Silva et al., “Multifunctional Chitosan / Gold Nanoparticles Coatings for Biomedical Textiles,” nanomaterials, vol. 1064, no. 9, pp. 1–21, 2019.

[14] W. Yandi et al., “Antialgal activity of poly(2- (dimethylamino)ethyl methacrylate) (PDMAEMA) brushes against the marine alga Ulva,” Biofouling, vol. 33, no. 2, pp. 169–183, 2017.

[15] N. O. Eddy, H. Momoh-Yahaya, and E. E. Oguzie, “Theoretical and experimental studies on the corrosion inhibition potentials of some purines for aluminum in 0.1 M HCl,” Journal of Advanced Research, vol. 6, no. 2, pp. 203–217, 2015. http://dx.

[16] A. De Mendonça Santos, T. F. De Almeida, F. Cotting, I. V. Aoki, H. G. De Melo, and V. R. Capelossi, “Evaluation of castor bark powder as a corrosion inhibitor for carbon steel in acidic media,” Materials Research, vol. 20, pp. 506– 511, 2017. http://dx. MR-2016-0963

[17] I. Aranaz et al., “Cosmetics and cosmeceutical applications of chitin, chitosan and their derivatives,” Polymers, vol. 10, no. 2, 2018.

[18] D. Jianglian, “Application of Chitosan Based Coating in Fruit and Vegetable Preservation: A Review,” Journal of Food Processing & Technology, vol. 04, no. 05, pp. 5–8, 2013.

[19] S. N. Dalhatu, K. A. Modu, A. Adamu, and H. M. Adamu, “Poly Acrylic-Chitosan Co-Polymer as Corrosion Inhibitor for Mild Steel in 0 . 5 M Hydrochloric Acid Solutions,” European Journal of Advanced Chemistry Research, vol. 3, no. 3, pp. 61–68, 2022.

[20] R. L. Thankamony et al., “Preparation of Highly Porous Polymer Membranes with Hierarchical Porous Structures via Spinodal Decomposition of Mixed Solvents with UCST Phase Behavior,” ACS Applied Materials and Interfaces, vol. 10, no. 50, pp. 44041–44049, 2018.

[21] D. Zeng, T. Chen, and S. Zhou, “Synthesis of polyaspartic acid/chitosan graft copolymer and evaluation of its scale inhibition and corrosion inhibition performance,” International Journal of Electrochemical Science, vol. 10, no. 11, pp. 9513–9527, 2015.

[22] M. Mobin, M. Rizvi, L. O. Olasunkanmi, and E. E. Ebenso, “Biopolymer from Tragacanth Gum as a Green Corrosion Inhibitor for Carbon Steel in 1 M HCl Solution,” ACS Omega, vol. 2, no. 7, pp. 3997–4008, 2017.

[23] Y. Liu, X. Shen, H. Zhou, Y. Wang, and L. Deng, “Chemical modification of chitosan film via surface grafting of citric acid molecular to promote the biomineralization,” Applied Surface Science, vol. 370, pp. 270–278, 2016.

[24] G. Z. Kyzas and D. N. Bikiaris, “Recent modifications of chitosan for adsorption applications: A critical and systematic review,” Marine Drugs, vol. 13, no. 1, pp. 312–337, 2015.

[25] G. Crini et al., “Cross-Linked Chitosan-Based Hydrogels for Dye Removal To cite this version : HAL Id : hal-02152909 Cross-Linked Chitosan-Based Hydrogels for Dye Removal,” Sustainable Agriculture Reviews, vol. 36, pp. 22–32, 2019.

[26] B. Li, J. Elango, and W. Wu, “Recent advancement of molecular structure and biomaterial function of chitosan from marine organisms for pharmaceutical and nutraceutical application,” Applied Sciences (Switzerland), vol. 10, no. 14, pp. 30–50, 2020.

[27] A. Tzereme, E. Christodoulou, G. Z. Kyzas, M. Kostoglou, D. N. Bikiaris, and D. A. Lambropoulou, “Chitosan grafted adsorbents for diclofenac pharmaceutical compound removal from single-component aqueous solutions and mixtures,” Polymers, vol. 11, no. 3, 2019.

[28] Y. O. Al-Ghamdi, K. A. Alamry, M. A. Hussein, H. M. Marwani, and A. M. Asiri, “Sulfone-modified chitosan as selective adsorbent for the extraction of toxic Hg(II) metal ions,” Adsorption Science and Technology, vol. 37, no. 1–2, pp. 139–159, 2019.

[29] N. Alemdar, “Synthesis of chitosan-based hydrogel by using photopolymerization technique,” Anadolu University Journal of Science and Technology-A Applied Sciences and Engineering, vol. 17, no. 2, pp. 391–400, 2016.

[30] L. Islas, G. Burillo, and A. Ortega, “Graft Copolymerization of 2 -Hydroxyethyl Methacrylate onto Chitosan Using Radiation Technique for Release of Diclofenac,” Macromolecular Research, vol. 26, no. 8, pp. 690–695, 2018.

[31] L. Wei et al., “Synthesis, characterization, and antifungal activity of pyridine-based triple quaternized chitosan derivatives,” Molecules, vol. 23, no. 10, 2018.

[32] A. M. Alsabagh, M. Z. Elsabee, Y. M. Moustafa, A. Elfky, and R. E. Morsi, “Corrosion inhibition efficiency of some hydrophobically modified chitosan surfactants in relation to their surface active properties,” Egyptian Journal of Petroleum, vol. 23, no. 4, pp. 349 –359, 2014. http://dx.

[33] U. Abdulganiyu, M. M. Saminu, and M. Aminu, “Graft copolymerization and characterization of styrene with chitosan via radical polymerization,” ChemSearch Journal, vol. 8, no. 1, pp. 56 –63, 2017. http://dx.

[34] M. K. Pati and P. Nayak, “Grafting Vinyl Monomers onto Chitosan:IV:Graft Copolymerized of Acrylicacid onto Chitosan Using Ceric Ammonium Nitrate as the Initiator— Characterization and Antimicrobial Activities,” Materials Sciences and Applications, vol. 02, no. 12, pp. 1741–1748, 2011.

[35] M. G. Tsoeunyane, M. E. Makhatha, and O. A. Arotiba, “Corrosion Inhibition of Mild Steel by Poly(butylene succinate)-L-histidine Extended with 1,6-diisocynatohexane Polymer Composite in 1 M HCl,” International Journal of Corrosion, vol. 5, no. 3, pp. 1–12, 2019. https://

[36] A. Sabarudin and A. D. R. Madjid, “Preparation and Kinetic Studies of Cross-Linked Chitosan Beads Using Dual Crosslinkers of Tripolyphosphate and Epichlorohydrin for Adsorption of Methyl Orange,” Scientific World Journal, vol. 2021, pp. 1 –11, 2021. https://

[37] N. A. Aljeaban et al., “Polymers Decorated with Functional Motifs for Mitigation of Steel Corrosion: An Overview,” International Journal of Polymer Science, vol. 2020, pp. 1– 23, 2020. https://

[38] S. R. Khairkar and A. R. Raut, “Synthesis of Chitosan-graft-Polyaniline-Based Composites,” American Journal of Materials Science and Engineering, vol. 2, no. 4, pp. 62–67, 2014. http://pubs.sciepub.com/ajmse/2/4/3

[39] H. M. Abd El-Salam, E. H. M. Kamal, and M. S. Ibrahim, “Synthesis and Characterization of Chitosan-Grafted-Poly(2-Hydroxyaniline) Microstructures for Water Decontamination,” Journal of Polymers and the Environment, vol. 25, no. 4, pp. 973–982, 2017.

[40] W. Mohd, E. Mustaqim, M. Daniyal, Y. W. Fen, S. Saleviter, and N. Chanlek, “X-ray Photoelectron Spectroscopy Analysis of Chitosan – Graphene Oxide-Based Composite Thin Films for Potential Optical Sensing Applications,” Polymers, vol. 13, no. 478, pp. 1–18, 2021. https://

[41] T. H. Ho, T. N. T. Le, T. A. Nguyen, and M. C. Dang, “Poly(ethylene glycol) grafted chitosan as new copolymer material for oral delivery of insulin,” Advances in Natural Sciences: Nanoscience and Nanotechnology, vol. 6, no. 3, 2015.

[42] M. S. Sakhare and H. H. Rajput, “Polymer Grafting And Applications In Pharmaceutical Drug Delivery Systems - A Brief Review,” vol. 10, no. 6, pp. 60 –67, 2017. http://dx. 72

[43] K. gounder Subramanian and V. Vijayakumar, “Synthesis and evaluation of chitosan-graft-poly (2-hydroxyethyl methacrylate-co-itaconic acid) as a drug carrier for controlled release of tramadol hydrochloride,” Saudi Pharmaceutical Journal, vol. 20, no. 3, pp. 263–271, 2012. http://dx.

[44] A. Almeida, D. Silva, V. Gonçalves, and B. Sarmento, “Synthesis and characterization of chitosan-grafted-polycaprolactone micelles for modulate intestinal paclitaxel delivery,” Drug Delivery and Translational Research, vol. 8, no. 2, pp. 387 –397, 2018. https:// 5

[45] D. R. Barleany, I. P. Alim, N. Rizkiyah, U. T. Lusi, H. Heriyanto, and E. Erizal, “International Conference on Technology, Innovation, and Society (ICTIS) 2016,” in Chitosan-Graft-Poly ( Acrylic Acid ) Superabsorbent Hydrogel with Antimicrobial Activity, 2016, no. 06, pp. 654– 661.

[46] O. F. A. Gawad, “Graft modification of carboxymethyl chitosan with styrene and its biological applications,” Beni-Suef University Journal of Basic and Applied Sciences (2020), vol. 9, no. 4, pp. 1–15, 2020.

[47] J. Yin, F. Wahid, Q. Zhang, Y. Tao, and C. Zhong, “Facile Incorporation of Silver Nanoparticles into Quaternized Poly ( 2- ( Dimethylamino ) Ethyl Methacrylate ) Brushes as Bifunctional Antibacterial Coatings,” no. March, 2017.

[48] E. I. Nkechinyere, Preparation and Characterization of Porous Chitosan Tripolyphosphate Gel Bead, no. August. 2014, pp. 1–20.

[49] J. Meng, J. Cui, S. Yu, H. Jiang, C. Zhong, and J. Hongshun, “Preparation of aminated chitosan microspheres by one-pot method and their adsorption properties for dye wastewater,” Royal Society Open Science, vol. 6, no. 5, 2019. https://dx. c.4486742

@article{1708666,
      author = {Sani Nazifi Dalhatu, Suleiman Yusuf Sule, Aminu Dabo Shuaibu, Ridwanu Murtala},
      title = {Review on the Applications of Modified Chitosan as an Alternative Novel Materials for Chemical Technology},
      journal = {Iconic Research And Engineering Journals},
      year = {2025},
      volume = {8},
      number = {11},
      pages = {1983-1991},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1708666.pdf},
      abstract = {The paper reviewed the applications of modified chitosan as alternative materials in chemical technology. It starts with an introduction to chitosan and the importance of modifications then discusses the different types of modified chitosan materials. The main body focuses on the diverse applications of these modified chitosan materials, such as water treatment, catalysis, drug delivery, and other emerging uses. The conclusion summarizes the key points and highlights future research directions.},
      keywords = {Chitin, Chitosan, Chitosan Derivatives, Chemical Technology, Novel materials},
      month = {May},
  }