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Remediation of Crude Oil Contaminated Soil Through Thermolysis and Electrokinetic Methods

John. E. Sani Kasimu Yusuf G. Moses

Subject area: Science,Engineering and Technology  ·  Area of research: Geotechnics

Abstract

This study investigates the remediation of crude oil-contaminated soil using thermolysis and electrokinetic techniques, focusing on their efficiency in removing contaminants and improving soil properties. Various remediation methods were tested, including thermal (T), electrokinetics (E), thermal-electrokinetics (TE), and electrokinetics-thermal (ET). Among these, the electrokinetics-thermal (ET) method demonstrated the highest efficiency, achieving a 39.4% removal of total petroleum hydrocarbons (TPH), with the lowest TPH removal of 18.9% using the thermal (T) method. The elemental analysis, conducted via X-Ray Fluorescence (XRF), indicated that oxygen and silicon were the most abundant elements, suggesting the presence of oxides and silicate minerals in the samples. The Maximum Dry Density (MDD) and Optimum Moisture Content (OMC) of the soil samples reveal moderate variations in moisture content across the treatments. The California Bearing Ratio (CBR) results indicated that the remediated soil samples, particularly those treated with thermal and electrokinetic combinations, exhibited enhanced load-bearing capacities, making them more suitable for construction applications compared to the untreated contaminated soil. The findings highlight the potential of integrated thermolysis and electrokinetics as effective remediation methods for improving the strength and environmental safety of contaminated soils.

Keywords

Contaminated Soil, Electrokinetics, Thermal, Maximum Dry Density (MDD) and Optimum Moisture Content (OMC), California Bearing Ratio (CBR).

References

[1] ADDIN Mendeley Bibliography CSL_BIBLIOGRAPHY Adeniran, M. A., Oladunjoye, M. A., & Doro, K. O. (2023). Soil and groundwater contamination by crude oil spillage: A review and implications for remediation projects in Nigeria. Frontiers in Environmental Science, 11(May). https://doi.org/10.3389/fenvs.2023.1137496

[2] Adeola, A. O., Akingboye, A. S., Ore, O. T., Oluwajana, O. A., Adewole, A. H., Olawade, D. B., & Ogunyele, A. C. (2022). Crude oil exploration in Africa: socio-economic implications, environmental impacts, and mitigation strategies. Environment Systems and Decisions, 42(1), 26–50. https://doi.org/10.1007/s10669-021-09827-x

[3] Azhar, A. T. S., Azim, M. A. M., Syakeera, N. N., Jefferson, I. F., & Rogers, C. D. F. (2017). Application of Electrokinetic Stabilisation (EKS) Method for Soft Soil: A Review. IOP Conference Series: Materials Science and Engineering, 226(1). https://doi.org/10.1088/1757-899X/226/1/012075

[4] Demcak, S., & Balintova, M. (2015). Overview of chosen techniques and methods for soils remediation. Technical University of Kosice, 1, 95–102.

[5] Han, D., Wu, X., Li, R., Tang, X., Xiao, S., & Scholz, M. (2021). Critical Review of Electro-kinetic Remediation of Contaminated Soils and Sediments: Mechanisms, Performances and Technologies. Water, Air, and Soil Pollution, 232(8). https://doi.org/10.1007/s11270-021-05182-4

[6] Ite, A. E., Harry, T. A., Obadimu, C. O., Asuaiko, E. R., & Inim, I. J. (2018). Petroleum hydrocarbons contamination of surface water and groundwater in the Niger Delta region of Nigeria. In Journal of Environment Pollution and Human Health (Vol. 6, Issue 2, pp. 51–61).

[7] Kang, C. U., Kim, D. H., Khan, M. A., Kumar, R., Ji, S. E., Choi, K. W., Paeng, K. J., Park, S., & Jeon, B. H. (2020). Pyrolytic remediation of crude oil-contaminated soil. Science of the Total Environment, 713. https://doi.org/10.1016/j.scitotenv.2020.136498

[8] Malekzadeh, M., & Nalbantoglu, Z. (2013). Electrokinetic Stabilization of Soft Clay. University of Birmingham, July, 1375–1381. https://doi.org/10.3850/978-981-07-3560-9_06-0602

[9] Prakash, A. A., Prabhu, N. S., Rajasekar, A., Parthipan, P., AlSalhi, M. S., Devanesan, S., & Govarthanan, M. (2021). Bio-electrokinetic remediation of crude oil contaminated soil enhanced by bacterial biosurfactant. In Journal of Hazardous Materials (Vol. 405). J Hazard Mater. Epub 2020 Oct 13. PMID: 33092887. https://doi.org/10.1016/j.jhazmat.2020.124061

[10] Sam, K., Coulon, F., & Prpich, G. (2017). Management of petroleum hydrocarbon contaminated sites in Nigeria: Current challenges and future direction. Land Use Policy, 64(October), 133–144. https://doi.org/10.1016/j.landusepol.2017.01.051

[11] Yeung, A. T. (2017). Remediation Technologies for Contaminated Sites (Issue January 2010). Proc., Int’l. Symp. on Geoenvironmental Engrg., ISGE2009. https://doi.org/10.1007/978-3-642-04460-1

[12] Moses, G., Etim, R. K., Sani, J. E., & Bobai, Y. S. (2019). Geotechnical Properties of Crude Oil Incinerated Lateritic Soil for Use in Roadwork. FUW Trends in Science & Technology Journal, Www.Ftstjournal. Com e-ISSN, 4(1), 69–074. www.ftstjournal.com

[13] Sani, J. E., Moses, G., & Musa, S. (2023). Physicochemical evaluation of coconut shell biochar remediation effect on crude oil contaminated soil. Cogent Engineering, 10(2). https://doi.org/10.1080/23311916.2023.2269659

How to cite this paper

John. E. Sani, Kasimu Yusuf, G. Moses "Remediation of Crude Oil Contaminated Soil Through Thermolysis and Electrokinetic Methods" Iconic Research And Engineering Journals Volume 8 Issue 12 2025 Page 982-990
John. E. Sani, Kasimu Yusuf, G. Moses "Remediation of Crude Oil Contaminated Soil Through Thermolysis and Electrokinetic Methods" Iconic Research And Engineering Journals, vol. 8, no. 12, Jun. 2025
John. E. Sani, Kasimu Yusuf, G. Moses (2025). Remediation of Crude Oil Contaminated Soil Through Thermolysis and Electrokinetic Methods. Iconic Research And Engineering Journals, 8(12).
John. E. Sani, Kasimu Yusuf, G. Moses "Remediation of Crude Oil Contaminated Soil Through Thermolysis and Electrokinetic Methods" Iconic Research And Engineering Journals, vol. 8, no. 12, Jun. 2025.
@article{1709171,
      author = {John. E. Sani, Kasimu Yusuf, G. Moses},
      title = {Remediation of Crude Oil Contaminated Soil Through Thermolysis and Electrokinetic Methods},
      journal = {Iconic Research And Engineering Journals},
      year = {2025},
      volume = {8},
      number = {12},
      pages = {982-990},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1709171.pdf},
      abstract = {This study investigates the remediation of crude oil-contaminated soil using thermolysis and electrokinetic techniques, focusing on their efficiency in removing contaminants and improving soil properties. Various remediation methods were tested, including thermal (T), electrokinetics (E), thermal-electrokinetics (TE), and electrokinetics-thermal (ET). Among these, the electrokinetics-thermal (ET) method demonstrated the highest efficiency, achieving a 39.4% removal of total petroleum hydrocarbons (TPH), with the lowest TPH removal of 18.9% using the thermal (T) method.  The elemental analysis, conducted via X-Ray Fluorescence (XRF), indicated that oxygen and silicon were the most abundant elements, suggesting the presence of oxides and silicate minerals in the samples. The Maximum Dry Density (MDD) and Optimum Moisture Content (OMC) of the soil samples reveal moderate variations in moisture content across the treatments. The California Bearing Ratio (CBR) results indicated that the remediated soil samples, particularly those treated with thermal and electrokinetic combinations, exhibited enhanced load-bearing capacities, making them more suitable for construction applications compared to the untreated contaminated soil. The findings highlight the potential of integrated thermolysis and electrokinetics as effective remediation methods for improving the strength and environmental safety of contaminated soils.},
      keywords = {Contaminated Soil, Electrokinetics, Thermal, Maximum Dry Density (MDD) and Optimum Moisture Content (OMC), California Bearing Ratio (CBR).},
      month = {June},
  }