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1716580 Vol 9 · Issue 10 Download Paper

The Influence of bifunctional Heterogeneous Catalyst on Biodiesel Production from Oleochemicals

Ifreke Akpan Ifeanyichukwu Edeh Lucky Uyigue

Subject area: Science,Engineering and Technology  ·  Area of research: Biodiesel Production

DOI: 10.64388/IREV9I10-1716580

Abstract

Over the years, production of biodiesel has gain momentum due to the advent of novel catalysts like bifunctional heterogeneous catalyst which is capable of catalyzing both esterification and transesterification reaction simultaneously through its multiple sites, and this save time, cost of production, materials utilization and most importantly production of biodiesel from oleochemicals with high free fatty acid. Thus, this study focused on the assessment of the efficiency of bifunctional heterogeneous catalyst (CaO/Al2O3) on biodiesel production using oleochemicals (Bush Mango Seed Oil (BMSO), African Native Pear Seed Oil (ANPSO) and Orange Peels Oil (OPO) as triglycerides. The bifunctional heterogeneous catalysts which were produced at various conditions of temperature, time and components mixing ratio (CaO: Al2O3) were used to catalyze the transesterification reaction in order to ascertain their efficacies. Among the tested catalyst, catalyst B yielded the highest percentage of biodiesel with 67.3%, 35.5 % and 60.2 % for ANPSO, BMSO and OPO respectively. Analysis of physicochemical properties of the biodiesel (flash point, cloud point, pour point, viscosity and density) showed that there are all within the range of acceptable values for biodiesel specified by ASTM6751.

Keywords

Oleochemical, Biodiesel, Bifunctional Catalyst, Energy, Transesterification Reaction.

References

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[2] Farouk, S. M., Tayeb, A. M., Abdel-Hamid, S. M., and Osman, R. M. (2024). Recent advances in transesterification for sustainable biodiesel production, challenges, and prospects: a comprehensive review. Environmental Science and Pollution Research, 31(9), 12722-12747.

[3] Suzihaque, M. U. H., Syazwina, N., Alwi, H., Ibrahim, U. K., Abdullah, S., and Haron, N. (2022). A sustainability study of the processing of kitchen waste as a potential source of biofuel: Biodiesel production from waste cooking oil (WCO). Materials Today: Proceedings, 63, S484-S489.

[4] Organization of Economic co-operation and Development report 2018

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[6] Latif, M. A. A., Yusof, A. A., Shukor, A. Z., Habidi, F. A., Nor, N. F. M., Akop, M. Z., and Roslizar, A. (2017). Nanostructure and oxidation properties investigation of engine using Jatropha biodiesel as engine fuel. In MATEC Web of Conferences (Vol. 90, p. 01046). EDP Sciences.

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[8] Akpan, I., Edeh, I and Uyigue, L. (2026). Characterization of functional Heterogeneous Catalyst Synthesized by Impregnating Calcium Oxide Derived from Periwinkle Shell with Refined Alumina. Iconic Research and Engineering Journals. Voume 9, issue 7. P. 2936- 2948.

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[10] Mohadesi, M., Aghel, B., Maleki, M., Ansari, A. (2020). Study of the Transesterification of Waste Cooking oil for the Production of Biodiesel in Microreactor Pilot. The effect of Acetone as the Co-solvent. Fuel. 273: 117736.

[11] Miyuranga, K. A. V., Arachchige, U. S. P. R., Marso, T. M. M., and Samarakoon, G. (2023). Biodiesel Production through the Transesterification of Waste Cooking Oil over Typical Heterogeneous Base or Acid Catalysts. Catalysts, 13(3), 546. https://doi.org/10.3390/catal13030546

How to cite this paper

Ifreke Akpan, Ifeanyichukwu Edeh, Lucky Uyigue "The Influence of bifunctional Heterogeneous Catalyst on Biodiesel Production from Oleochemicals" Iconic Research And Engineering Journals Volume 9 Issue 10 2026 Page 1864-1870 https://doi.org/10.64388/IREV9I10-1716580
Ifreke Akpan, Ifeanyichukwu Edeh, Lucky Uyigue "The Influence of bifunctional Heterogeneous Catalyst on Biodiesel Production from Oleochemicals" Iconic Research And Engineering Journals, vol. 9, no. 10, Apr. 2026, doi: https://doi.org/10.64388/IREV9I10-1716580
Ifreke Akpan, Ifeanyichukwu Edeh, Lucky Uyigue (2026). The Influence of bifunctional Heterogeneous Catalyst on Biodiesel Production from Oleochemicals. Iconic Research And Engineering Journals, 9(10). doi: https://doi.org/10.64388/IREV9I10-1716580
Ifreke Akpan, Ifeanyichukwu Edeh, Lucky Uyigue "The Influence of bifunctional Heterogeneous Catalyst on Biodiesel Production from Oleochemicals" Iconic Research And Engineering Journals, vol. 9, no. 10, Apr. 2026. Crossref, https://doi.org/10.64388/IREV9I10-1716580
@article{1716580,
      author = {Ifreke Akpan, Ifeanyichukwu Edeh, Lucky Uyigue},
      title = {The Influence of bifunctional Heterogeneous Catalyst on Biodiesel Production from Oleochemicals},
      journal = {Iconic Research And Engineering Journals},
      year = {2026},
      volume = {9},
      number = {10},
      pages = {1864-1870},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1716580.pdf},
      abstract = {Over the years, production of biodiesel has gain momentum due to the advent of novel catalysts like bifunctional heterogeneous catalyst which is capable of catalyzing both esterification and transesterification reaction simultaneously through its multiple sites, and this save time, cost of production, materials utilization and most importantly production of biodiesel from oleochemicals with high free fatty acid. Thus, this study focused on the assessment of the efficiency of bifunctional heterogeneous catalyst (CaO/Al2O3) on biodiesel production using oleochemicals (Bush Mango Seed Oil (BMSO), African Native Pear Seed Oil (ANPSO) and Orange Peels Oil (OPO) as triglycerides. The bifunctional heterogeneous catalysts which were produced at various conditions of temperature, time and components mixing ratio (CaO: Al2O3) were used to catalyze the  transesterification reaction in order to ascertain their efficacies. Among the tested catalyst, catalyst B yielded the highest percentage of biodiesel with 67.3%, 35.5 % and 60.2 % for ANPSO, BMSO and OPO respectively. Analysis of physicochemical properties of the biodiesel (flash point, cloud point, pour point, viscosity and density) showed that there are all within the range of acceptable values for biodiesel specified by ASTM6751.},
      keywords = {Oleochemical, Biodiesel, Bifunctional Catalyst, Energy, Transesterification Reaction.},
      month = {April},
      doi = {https://doi.org/10.64388/IREV9I10-1716580}
  }