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Development Of an Al-4.1%Cu-1.7%Mg Alloy Reinforced with Periwinkle Shell Ash (Turritella Communis) Particulate for Lightweight Engineering Applications
Subject area: Science,Engineering and Technology · Area of research: Nwabufoh Anthony
DOI: https://doi.org/10.64388/IREV10I1-1719957
Abstract
It was investigated in this study how a periwinkle shell ash (PSA) reinforced Al-4.1%Cu-1.7%Mg alloy can be developed for lightweight engineering applications. Ash from the periwinkle shells (Turritella communis) collected from Calabar, Nigeria and calcined at 1200°C for 5 hours was characterised using X-ray fluorescence (XRF) and X-ray diffraction (XRD). CaO (40.84%), SiO₂ (32.84%), Al₂O₃ (10.20%), and Fe₂O₃ (7.02%) made up the majority of the ash, according to XRF analysis. The composites 0 wt % PSA, 5 wt % PSA, 10 wt % PSA, 15 wt % PSA, 20 wt % PSA, 25 wt % PSA and composite of 30 wt % PSA were produced by double stir casting process. Standard procedures were employed to estimate the mechanical parameters (impact energy, yield strength, ultimate tensile strength and hardness) and physical qualities (density and porosity). Data was collected three times for each test and analysed using both Python and MINITAB. The results showed that the porosity increasingly changed from 0.09% to 0.33% and the density increasingly changed from 2.93 to 2.60 g/cm³ (11.3%), as the concentration of PSA increased. Hardness rose by 58.2%, from 55.47 to 87.73 HRF. Ultimately, the strength of the material in terms of ultimate tensile strength (UTS) showed an increase up to 25 weight percent PSA (31.7% increase) before again dropping at 30 weight percent PSA (w/PSA). This trend was also observed for yield strength (maximum of 151.60 N/mm2 with 25 weight percent of PSA (31.2% higher) and impact energy (a decrease from 10.00 to 4.80 J, 52.0% lower). It was observed that over the optimum PSA concentration of 25 wt. percent, performance was hindered by particle agglomeration. Response Surface Methodology (RSM) was used to perform multi-response characterisation of the composite and to generate contour plots and 3D surface graphs, and to do desirability optimisation to confirm the optimum reinforcement content. Indubitably, the statistical analysis (ANOVA and Tukey HSD) indicated that the PSA concentration had significant effects (p < 0.05) on all the properties evaluated. In this work, periwinkle shell ash which is a common farm waste was determined to be a low-cost and low-energy-consuming reinforcement for Al-Cu-Mg alloys.
Keywords
Composite, Engineering, Metals, Periwinkle Shell
References
[1] Adah, P. U., Nuhu, A. A., Salawu, A. A., Hassan, A. B., & Ubi, P. A. (2024). Characterization of periwinkle shell ash reinforced polymer composite for automotive application. Fudma Journal of Sciences, 8(1), 83–92.
[2] Akande, I. G., Kazeem, R. A., Jen, T.-C., Daramola, O. M., & Akinlabi, E. T. (2024). Development of Automotive and Marine Appliable Aluminium Composite by Utilizing Agro-Waste Material as Performance Enhancement Particles. Journal of Bio- and Tribo-Corrosion, 10(4), 114. https://doi.org/10.1007/s40735-024-00915-4
[3] Bowen L. (2024) Multi-objective optimization of multifunctional composite laminates for improved microwave absorbing and load bearing capacity. Mater Today Commun. 38:108019
[4] Cai, Y., Su, Y., Liu, K., Hua, A., Wang, X., Cao, H., Zhang, D., & Ouyang, Q. (2023). Effect of Sc microalloying on fabrication, microstructure and mechanical properties of SiCp/Al–Cu–Mg-Sc composites via powder metallurgy. Materials Science and Engineering: A, 877, 145152.
[5] Callister W.D. and Rethwish D.G.(2020) Mechanical Properties of Metals, Material Science and Engineering Wiley 9th Edition Pp 168
[6] Cullity B.D. and Stock S.R. (2014) Elements of X-ray Diffraction 3rd edition. Pearson Education Limited
[7] Ekop, I. E., Simonyan, K. J., & Onwuka, U. N. (2021). Effects of processing factors and conditions on the cracking efficiency of Tympanotonus fuscatus and Pachymelania aurita periwinkles: Response surface approach. Journal of Agriculture and Food Research, 3, 100094.
[8] Goldstein B.A., Newbury D.E., Michael J.R., Ritchie N.W.M. , Scott H.J. and Joy D. C. (2017) Scanning Electron Microscopy and X-ray Microanalysis. Springer New York
[9] Gudipudi, S., Nagamuthu, S., Subbian, K. S., & Chilakalapalli, S. P. R. (2020). Enhanced mechanical properties of AA6061-B4C composites developed by a novel ultra-sonic assisted stir casting. Engineering Science and Technology, an International Journal, 23(5), 1233–1243.
[10] Han, X., Wang, S., Wei, B., Pan, S., Liao, G., Li, W., & Wei, Y. (2022). Influence of Sc Addition on Precipitation Behavior and Properties of Al-Cu-Mg Alloy. Acta Metallurgica Sinica (English Letters), 35(6), 948–960. https://doi.org/10.1007/s40195-021-01328-9
[11] Ituen, E. U. (2020). Mechanical and chemical properties of selected mullusc shells in Nigeria. International Journal of Agricultural Policy and Research, 3(1), 53–59.
[12] Kumar, D., & Thakur, L. (2023). Investigation on Mechanical and Wear Performance of Ultrasonic-Assisted Stir Cast AZ91D/Al2O3 Magnesium Matrix Composites. Metals and Materials International, 29(9), 2767–2781. https://doi.org/10.1007/s12540-023-01395-w
[13] Nie, K. B., Wang, X. J., Deng, K. K., Hu, X. S., & Wu, K. (2021). Magnesium matrix composite reinforced by nanoparticles – A review. Journal of Magnesium and Alloys, 9(1), 57–77. https://doi.org/10.1016/j.jma.2020.08.018
[14] Onuoha, C., Onyemaobi, O. O., Anyakwo, C. N., & Onuegbu, G. C. (2017). Physical and morphological properties of periwinkle shell-filled recycled polypropylene composites. International Journal of Innovative Science, Engineering and Technology, 4(5), 186–196.
[15] Orji, F., Egwuonwu, C., & Asoegwu, S. (2017). The investigation of periwinkle shell-rice husk composite as a replacement for granite in concrete. Open Science Journal of Bioscience and Bioengineering, 4(1), 1–5.
[16] Otunyo, A. W., Friday, I. U., & Israel, T. A. (2013). Exploratory study of crushed periwinkle shell as partial replacement for fine aggregates in concrete. Journal of Emerging Trends in Engineering and Applied Sciences, 4(6), 823–827.
[17] Pillari, L. K., Lessoway, K., & Bichler, L. (2024). Reciprocating dry sliding friction and wear behavior of B319 aluminum alloy-graphene composites. Tribology International, 192, 109334. https://doi.org/10.1016/j.triboint.2024.109334
[18] Polmear I., StJohn D., Nie J. and Qian Ma (2017) Light alloys: Metallurgy of the light Metals (5th Edition). Elseiver / Butterworth -Heinemann Publisher
[19] Saeed, E., Ogundiran, M. B., Goracci, G., Aymonier, C., & Dolado, J. S. (2025). Supplementary Cementitious Materials Based on CO2 –Capturing Periwinkle Shell. ACS Sustainable Resource Management, 2(11), 2197–2205. https://doi.org/10.1021/acssusresmgt.5c00313
[20] Sankhla, A., & Patel, K. M. (2022). Metal Matrix Composites Fabricated by Stir Casting Process–A Review. Advances in Materials and Processing Technologies, 8(2), 1270–1291. https://doi.org/10.1080/2374068X.2020.1855404
[21] Tobins, F. H., Abubakre, O. K., Muriana, R. A., & Abdulrahman, A. S. (2018). Snail shell as an inspiring engineering material in science and technology development: A review. http://irepo.futminna.edu.ng:8080/jspui/handle/123456789/19584
[22] Ubi, P. A., Adah, P. U., Ademoh, N. A., Salawu, A. A., Hassan, A. B., Dashe, J. D., & Oyeyemi, S. W. (2022). Rice husk ash reinforced natural rubber composites: Effect of benzene diazonium salt treatment. Nigerian Journal of Technology, 41(5), 879–886.
[23] Umaru, O. B., Abdulwahab, M., Tokan, A., Onoriode, A., & Mohammed, Y. (2019). Effect Of Isothermal Heat Treatment On The Hardness And Microstructural Study Of Aluminium/Periwinkle Shell Ash Bio Composite. International Journal of Research in Advanced Engineering and Technology ISSN, 2455–0876.
[24] Umunakwe, R., Olaleye, D. J., Oyetunji, A., Okoye, O. C., & Umunakwe, I. J. (2017). Assessment of some mechanical properties and microstructure of particulate periwinkle shell-aluminium 6063 metal matrix composite (PPS-ALMMC) produced by two-step casting. Nigerian Journal of Technology, 36(2), 421–427.
[25] Wang, F., Liu, H., Liu, Z., Guo, Z., & Sun, F. (2022). Microstructure analysis, tribological correlation properties and strengthening mechanism of graphene reinforced aluminum matrix composites. Scientific Reports, 12(1), 9561.
[26] Yuan, L., Liu, F., Wu, C., & Lou, C. (2025). Improving mechanical properties and electrical conductivity of Al-Cu-Mg matrix composites by GNPs and sc additions. Scientific Reports, 15(1), 2418.
How to cite this paper
@article{1719957,
author = {Nwabufoh Ogochukwu Anthony, Dr. Chukwuemeka Ezechukwu, Nwabufoh Nebeolisa},
title = {Development Of an Al-4.1%Cu-1.7%Mg Alloy Reinforced with Periwinkle Shell Ash (Turritella Communis) Particulate for Lightweight Engineering Applications},
journal = {Iconic Research And Engineering Journals},
year = {2026},
volume = {10},
number = {1},
pages = {3031-3042},
issn = {2456-8880},
url = {https://www.irejournals.com/formatedpaper/1719957.pdf},
abstract = {It was investigated in this study how a periwinkle shell ash (PSA) reinforced Al-4.1%Cu-1.7%Mg alloy can be developed for lightweight engineering applications. Ash from the periwinkle shells (Turritella communis) collected from Calabar, Nigeria and calcined at 1200°C for 5 hours was characterised using X-ray fluorescence (XRF) and X-ray diffraction (XRD). CaO (40.84%), SiO₂ (32.84%), Al₂O₃ (10.20%), and Fe₂O₃ (7.02%) made up the majority of the ash, according to XRF analysis. The composites 0 wt % PSA, 5 wt % PSA, 10 wt % PSA, 15 wt % PSA, 20 wt % PSA, 25 wt % PSA and composite of 30 wt % PSA were produced by double stir casting process. Standard procedures were employed to estimate the mechanical parameters (impact energy, yield strength, ultimate tensile strength and hardness) and physical qualities (density and porosity). Data was collected three times for each test and analysed using both Python and MINITAB. The results showed that the porosity increasingly changed from 0.09% to 0.33% and the density increasingly changed from 2.93 to 2.60 g/cm³ (11.3%), as the concentration of PSA increased. Hardness rose by 58.2%, from 55.47 to 87.73 HRF. Ultimately, the strength of the material in terms of ultimate tensile strength (UTS) showed an increase up to 25 weight percent PSA (31.7% increase) before again dropping at 30 weight percent PSA (w/PSA). This trend was also observed for yield strength (maximum of 151.60 N/mm2 with 25 weight percent of PSA (31.2% higher) and impact energy (a decrease from 10.00 to 4.80 J, 52.0% lower). It was observed that over the optimum PSA concentration of 25 wt. percent, performance was hindered by particle agglomeration. Response Surface Methodology (RSM) was used to perform multi-response characterisation of the composite and to generate contour plots and 3D surface graphs, and to do desirability optimisation to confirm the optimum reinforcement content. Indubitably, the statistical analysis (ANOVA and Tukey HSD) indicated that the PSA concentration had significant effects (p < 0.05) on all the properties evaluated. In this work, periwinkle shell ash which is a common farm waste was determined to be a low-cost and low-energy-consuming reinforcement for Al-Cu-Mg alloys.},
keywords = {Composite, Engineering, Metals, Periwinkle Shell},
month = {July},
doi = {https://doi.org/10.64388/IREV10I1-1719957}
}