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1709477 Vol 9 · Issue 1 Download Paper

Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System

Miriam Wanjiru Kinuthia Eric Njagi Ochieng Ombaka Zachery Getenga

Subject area: Science,Engineering and Technology  ·  Area of research: Inorganic Chemistry

Abstract

Mixed-metal oxides are promising adsorbents for removal of methylene blue from waste streams due to their excellent textural and thermal properties. In this study, a CuO-TiO2-ZrO2 (5-47.5-47.5) ternary oxide was synthesized using the Pechini method and evaluated for adsorptive removal of methylene blue from aqueous solutions. The structural properties of the ternary oxide were determined using powder X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. Morphological properties were determined using scanning electron microscopy (SEM) while elemental analysis was done using energy dispersive X-ray (EDX) spectroscopy. The synthesized ternary oxide was poorly crystalline with copper oxide in a highly dispersed and amorphous state. The oxide consisted of irregular-shaped particles of different sizes that tended to agglomerate. The oxide was effective for adsorption of methylene blue. The optimal adsorption conditions were: a pH of 6, contact time of 20 min, dosage of 0.2 g and temperature of 45?C. The adsorption process was pseudo second order and fitted Langmuir and Temkin isotherms. The synthesized ternary oxide is a promising adsorbent for removal of methylene blue from aqueous solutions.

Keywords

CuO-ZrO?-TiO?, ternary oxides, adsorption, methylene blue, dyes

References

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How to cite this paper

Miriam Wanjiru Kinuthia, Eric Njagi, Ochieng Ombaka, Zachery Getenga "Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System" Iconic Research And Engineering Journals Volume 9 Issue 1 2025 Page 159-169
Miriam Wanjiru Kinuthia, Eric Njagi, Ochieng Ombaka, Zachery Getenga "Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System" Iconic Research And Engineering Journals, vol. 9, no. 1, Jul. 2025
Miriam Wanjiru Kinuthia, Eric Njagi, Ochieng Ombaka, Zachery Getenga (2025). Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System. Iconic Research And Engineering Journals, 9(1).
Miriam Wanjiru Kinuthia, Eric Njagi, Ochieng Ombaka, Zachery Getenga "Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System" Iconic Research And Engineering Journals, vol. 9, no. 1, Jul. 2025.
@article{1709477,
      author = {Miriam Wanjiru Kinuthia, Eric Njagi, Ochieng Ombaka, Zachery Getenga},
      title = {Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System},
      journal = {Iconic Research And Engineering Journals},
      year = {2025},
      volume = {9},
      number = {1},
      pages = {159-169},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1709477.pdf},
      abstract = {Mixed-metal oxides are promising adsorbents for removal of methylene blue from waste streams due to their excellent textural and thermal properties. In this study, a CuO-TiO2-ZrO2 (5-47.5-47.5) ternary oxide was synthesized using the Pechini method and evaluated for adsorptive removal of methylene blue from aqueous solutions. The structural properties of the ternary oxide were determined using powder X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. Morphological properties were determined using scanning electron microscopy (SEM) while elemental analysis was done using energy dispersive X-ray (EDX) spectroscopy. The synthesized ternary oxide was poorly crystalline with copper oxide in a highly dispersed and amorphous state. The oxide consisted of irregular-shaped particles of different sizes that tended to agglomerate. The oxide was effective for adsorption of methylene blue. The optimal adsorption conditions were: a pH of 6, contact time of 20 min, dosage of 0.2 g and temperature of 45?C. The adsorption process was pseudo second order and fitted Langmuir and Temkin isotherms. The synthesized ternary oxide is a promising adsorbent for removal of methylene blue from aqueous solutions.},
      keywords = {CuO-ZrO?-TiO?, ternary oxides, adsorption, methylene blue, dyes},
      month = {July},
  }