Home / Current Issue / Paper 1709477
Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System
Subject area: Science,Engineering and Technology · Area of research: Inorganic Chemistry
Abstract
Mixed-metal oxides are promising adsorbents for removal of methylene blue from waste streams due to their excellent textural and thermal properties. In this study, a CuO-TiO2-ZrO2 (5-47.5-47.5) ternary oxide was synthesized using the Pechini method and evaluated for adsorptive removal of methylene blue from aqueous solutions. The structural properties of the ternary oxide were determined using powder X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. Morphological properties were determined using scanning electron microscopy (SEM) while elemental analysis was done using energy dispersive X-ray (EDX) spectroscopy. The synthesized ternary oxide was poorly crystalline with copper oxide in a highly dispersed and amorphous state. The oxide consisted of irregular-shaped particles of different sizes that tended to agglomerate. The oxide was effective for adsorption of methylene blue. The optimal adsorption conditions were: a pH of 6, contact time of 20 min, dosage of 0.2 g and temperature of 45?C. The adsorption process was pseudo second order and fitted Langmuir and Temkin isotherms. The synthesized ternary oxide is a promising adsorbent for removal of methylene blue from aqueous solutions.
Keywords
CuO-ZrO?-TiO?, ternary oxides, adsorption, methylene blue, dyes
References
[1] Anzures, F. M., Rivas, F. C., Ventura, J. H., Hernández, P. S., Berlier, G., & Zacahua- Tlacuatl, G. (2015). Spectroscopic characterization of CuOx/TiO2-ZrO2 catalysts prepared by a-step sol-gel method. Applied Catalysis A: General, 489, 218-225.
[2] Bal, G., & Thakur, A. (2022). Distinct approaches of removal of dyes from wastewater: A review. Materials Today: Proceedings, 50, 1575-1579.
[3] Balcha, A., Yadav, O. P., & Dey, T. (2016). Photocatalytic degradation of methylene blue dye by zinc oxide nanoparticles obtained from precipitation and sol -gel methods. Environmental Science and Pollution Research, 23, 25485-25493.
[4] Dimesso, L. (2016). Pechini processes: an alternate approach of the sol–gel method, preparation, properties, and applications. In: L. Klein, M. Aparicio & A. Jitianu (Eds.). Handbook of sol-gel science and technology (pp. 1-22). Springer.
[5] Farooq, S., Al Maani, A. H., Naureen, Z., Hussain, J., Siddiqa, A., & Al Harrasi, A. (2022). Synthesis and characterization of copper oxide-loaded activated carbon nanocomposite: Adsorption of methylene blue, kinetic, isotherm, and thermodynamic study. Journal of Water Process Engineering, 47, 102692.
[6] Fouda, A., Salem, S. S., Wassel, A. R., Hamza, M. F., & Shaheen, T. I. (2020). Optimization of green biosynthesized visible light active CuO/ZnO nano-photocatalysts for the degradation of organic methylene blue dye. Heliyon, 6(9), e05073.
[7] Gadekar, M. R., & Ahammed, M. M. (2016). Coagulation/flocculation process for dye removal using water treatment residuals: modelling through artificial neural networks. Desalination and Water Treatment, 57(55), 26392-26400.
[8] Gomaa, H., Hussein, M. A., Motawea, M. M., Aboraia, A. M., Cheira, M. F., Alotaibi, M. T., ... & Ali, H. M. (2022). A hybrid mesoporous CuO@ barley straw -derived SiO 2 nanocomposite for adsorption and photocatalytic degradation of methylene blue from real wastewater. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 644, 128811.
[9] Honarmand, M. M., Mehr, M. E., Yarahmadi, M., & Siadati, M. H. (2019). Effects of different surfactants on morphology of TiO2 and Zr- doped TiO2 nanoparticles and their applications in MB dye photocatalytic degradation. SN Applied Sciences, 1, 1-12.
[10] Hosny, N. M., Gomaa, I., & Elmahgary, M. G. (2023). Adsorption of polluted dyes from water by transition metal oxides: A review. Applied Surface Science Advances, 15, 100395.
[11] Khan, I., Saeed, K., Zekker, I., Zhang, B., Hendi, A. H., Ahmad, A., ... & Khan, I. (2022). Review on methylene blue: Its properties, uses, toxicity and photodegradation. Water, 14(2), 242.
[12] Liu, H., Zhang, J., Lu, M., Liang, L., Zhang, H., & Wei, J. (2020). Biosynthesis based membrane filtration coupled with iron nanoparticles reduction process in removal of dyes. Chemical Engineering Journal, 387, 124202.
[13] Loutfi, M., Mariouch, R., Mariouch, I., Belfaquir, M., & ElYoubi, M. S. (2023). Adsorption of methylene blue dye from aqueous solutions onto natural clay: Equilibrium and kinetic studies. Materials Today: Proceedings, 72, 3638-3643.
[14] Lu, K., Wang, T., Zhai, L., Wu, W., Dong, S., Gao, S., & Mao, L. (2019). Adsorption behavior and mechanism of Fe-Mn binary oxide nanoparticles: Adsorption of methylene blue. Journal of Colloid and Interface Science, 539, 553-562.
[15] Maheshwari, K., Agrawal, M., & Gupta, A. B. (2021). Dye pollution in water and wastewater. Novel materials for dye-containing wastewater treatment, 1-25.
[16] Mani, S., Chowdhary, P., & Bharagava, R. N. (2019). Textile wastewater dyes: toxicity profile and treatment approaches. Emerging and eco- friendly approaches for waste management, 219-244.
[17] Mbachu, C. A., Babayemi, A. K., Egbosiuba, T. C., Ike, J. I., Ani, I. J., & Mustapha, S. (2023). Green synthesis of iron oxide nanoparticles by Taguchi design of experiment method for effective adsorption of methylene blue and methyl orange from textile wastewater. Results in Engineering, 19, 101198.
[18] Mi, B., Wang, J., Xiang, H., Liang, F., Yang, J., Feng, Z., ... & Fei, B. (2019). Nitrogen self- doped activated carbons derived from bamboo shoots as adsorbent for methylene blue adsorption. Molecules, 24(16), 3012.
[19] Mileva, A., Tsoncheva, T., Issa, G., Dimitrov, M., Kovacheva, D., & Henych, J. (2019). Mesoporous nanostructured copper-zirconium- titanium mixed oxides as catalysts for hydrogen production: effect of phase composition. Proceedings of the 8 th Serbian-Croatian- Slovenian Symposium on Zeolites [3 - 5 October 2019, Belgrade, Serbia].
[20] Morales-Anzures, F., Salinas-Hernández, P., Ornelas-Gutiérrez, C., Tzompantzi-Morales, F. J., & Pérez-Hernández, R. (2020). Synthesis by the sol-gel method and characterization of Pt- promoted CuO/TiO2-ZrO2 catalysts for decomposition of 2-propanol. Catalysis Today, 349, 228-234.
[21] Mouni, L., Belkhiri, L., Bollinger, J. C., Bouzaza, A., Assadi, A., Tirri, A., ... & Remini, H. (2018). Removal of Methylene Blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies. Applied Clay Science, 153, 38-45.
[22] Nas, M. S. (2021). AgFe 2O4/MWCNT nanoparticles as novel catalyst combined adsorption-sonocatalytic for the degradation of methylene blue under ultrasonic irradiation. Journal of Environmental Chemical Engineering, 9(3), 105207.
[23] Natarajan, S., Bajaj, H. C., & Tayade, R. J. (2018). Recent advances based on the synergetic effect of adsorption for removal of dyes from waste water using photocatalytic process. Journal of Environmental Sciences, 65, 201-222.
[24] Oladoye, P. O., Ajiboye, T. O., Omotola, E. O., & Oyewola, O. J. (2022). Methylene blue dye: Toxicity and potential elimination technology from wastewater. Results in Engineering, 16, 100678.
[25] Pourramezan, E., Omidvar, M., Motavalizadehkakhky, A., Zhiani, R., & Darzi, H. H. (2024). Enhanced adsorptive removal of methylene blue using ternary nanometal oxides in an aqueous solution. Biomass Conversion and Biorefinery, 1-13.
[26] Ramutshatsha-Makhwedzha, D., & Nomngongo, P. N. (2022). Application of ultrafiltration membrane technology for removal of dyes from wastewater. Membrane Based Methods for Dye Containing Wastewater: Recent Advances, 37-47.
[27] Reddy, B. M., Chowdhury, B., Ganesh, I., Reddy, E. P., Rojas, T. C., & Fernandez, A. (1998). Characterization of V2O5/TiO2-ZrO2 catalysts by XPS and other techniques. The Journal of Physical Chemistry B, 102(50), 10176-10182.
[28] Ruíz-Santoyo, V., Marañon-Ruiz, V. F., Romero-Toledo, R., González Vargas, O. A., & Pérez-Larios, A. (2021). Photocatalytic degradation of rhodamine b and methylene orange using TiO2-ZrO2 as nanocomposite, Catalysts, 11(9), 1035.
[29] Shih, M. C. (2012). Kinetics of the batch adsorption of methylene blue from aqueous solutions onto rice husk: effect of acid-modified process and dye concentration. Desalination and Water Treatment, 37(1-3), 200-214.
[30] Silva, G. C., Ciminelli, V. S., Ferreira, A. M., Pissolati, N. C., Paiva, P. R. P., & López, J. L. (2014). A facile synthesis of Mn3O4/Fe3O4 superparamagnetic nanocomposites by chemical precipitation: Characterization and application in dye degradation. Materials Research Bulletin, 49, 544-551.
[31] Tomar, T., Kahandawala, N., Kaur, J., Thounaojam, L., Choudhary, I., & Bera, S. (2023). Bioremediation of synthetic dyes from wastewater by using microbial nanocomposites: An emerging field for water pollution management. Biocatalysis and Agricultural Biotechnology, 51, 102767.
[32] Toro, R. G., Diab, M., de Caro, T., Al-Shemy, M., Adel, A., & Caschera, D. (2020). Study of the effect of titanium dioxide hydrosol on the photocatalytic and mechanical properties of paper sheets. Materials, 13(6), 1326.
[33] Wang, Q., Deng, W., Lin, X., Huang, X., Wei, L., Gong, L., ... & Liu, Q. (2021). Solid-state preparation of mesoporous Ce–Mn–Co ternary mixed oxide nanoparticles for catalytic degradation of methylene blue. Journal of Rare Earths, 39(7), 826-834.
[34] Yadav, S., & Sharma, A. (2021). Importance and challenges of hydrothermal technique for synthesis of transition metal oxides and composites as supercapacitor electrode materials. Journal of Energy Storage, 44, 103295.
[35] Yadav, R., Chundawat, T. S., Surolia, P. K., & Vaya, D. (2022). Photocatalytic degradation of textile dyes using β -CD-CuO/ZnO nanocomposite. Journal of Physics and Chemistry of Solids, 165, 110691.
[36] Yagub, M. T., Sen, T. K., Afroze, S., & Ang, H. M. (2014). Dye and its removal from aqueous solution by adsorption: a review. Advances in colloid and interface science, 209, 172-184.
[37] Yu, M., Dong, H., Zheng, Y., & Liu, W. (2021). Ternary metal oxide embedded carbon derived from metal organic frameworks for adsorption of methylene blue and acid red 73. Chemosphere, 280, 130567.
How to cite this paper
@article{1709477,
author = {Miriam Wanjiru Kinuthia, Eric Njagi, Ochieng Ombaka, Zachery Getenga},
title = {Efficient Removal of Methylene Blue from Aqueous Solutions Using a Copper Oxide-Zirconia -Titania Ternary System},
journal = {Iconic Research And Engineering Journals},
year = {2025},
volume = {9},
number = {1},
pages = {159-169},
issn = {2456-8880},
url = {https://www.irejournals.com/formatedpaper/1709477.pdf},
abstract = {Mixed-metal oxides are promising adsorbents for removal of methylene blue from waste streams due to their excellent textural and thermal properties. In this study, a CuO-TiO2-ZrO2 (5-47.5-47.5) ternary oxide was synthesized using the Pechini method and evaluated for adsorptive removal of methylene blue from aqueous solutions. The structural properties of the ternary oxide were determined using powder X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. Morphological properties were determined using scanning electron microscopy (SEM) while elemental analysis was done using energy dispersive X-ray (EDX) spectroscopy. The synthesized ternary oxide was poorly crystalline with copper oxide in a highly dispersed and amorphous state. The oxide consisted of irregular-shaped particles of different sizes that tended to agglomerate. The oxide was effective for adsorption of methylene blue. The optimal adsorption conditions were: a pH of 6, contact time of 20 min, dosage of 0.2 g and temperature of 45?C. The adsorption process was pseudo second order and fitted Langmuir and Temkin isotherms. The synthesized ternary oxide is a promising adsorbent for removal of methylene blue from aqueous solutions.},
keywords = {CuO-ZrO?-TiO?, ternary oxides, adsorption, methylene blue, dyes},
month = {July},
}