X-Ray Photoelectron Spectroscopy (XPS) Spectra Characterization of Mild Steel Corrosion in Carbon Dioxide (CO2) Deaerated Environment.

References

[1] G.H.Koch, M.P.H.B., N.G.Thompson,Y.P.Virmani, and J.H.Payer, Corrosion Cost and Preventon Strategies in the United States. Federal highway administration, U.S. Department of Transportation: McLean VA., 2002.

[2] Kermani, M.B. and D. Harrop, The Impact of Corrosion on Oil and Gas Industry.

[3] Schmitt, G. and M. Horstemeier, Fundamental Aspects of CO2 Metal Loss Corrosion

[4] Part II: Influence of Different Parameters on CO2 Corrosion Mechanisms. 2015, NACE International.

[5] Roberge, P.R., Corrosion basics: An introduction. 2006, NACE Press Book. p. 56-70.

[6] Nešić, S., Carbon Dioxide Corrosion of Mild Steel, in Uhlig's Corrosion Handbook. 2011, John Wiley & Sons, Inc. p. 229-245.

[7] Venkatraman, M.S., et al. Modeling corrosion of a metal under an aerosol droplet. in

[8] Materials Science Forum. 2010. Trans Tech Publications.

[9] Gunaltun, Y. and L. Payne, A New Technique for the Control of Top of the Line Cor- rosion: TLCC-PIG. NACE International.

[10] Abayarathna, D., A. Naraghi, and N. Obeyesekere, Inhibition of Corrosion of Carbon Steel in the Presence of CO2, H2S and S. NACE International.

[11] Gulbrandsen, E., et al., Effect of Precorrosion on the Performance of Inhibitors for CO2 Corrosion of Carbon Steel. NACE International.

[12] Pourbaix, M., Atlas of electrochemical equilibria in aqueous solutions. 1974: National Association of Corrosion Engineers.

[13] Vanloon, G.D., S, Environmental chemistry - a global perspective. 2011, Oxford Uni- versity Press. p. 235-248.

[14] Bardal, E., Corrosion and Protection. 2004: Springer.

[15] Tait, W.S., An Introduction to electrochemical corrosion testing for practicing engi- neers and scientists. 1994, Pair Docs Publications.

[16] C.A Barlow, J., The Electrical Double Layer in physical chemistry: An Advanced Treatise, in Electrochemistry. 1970, Academic press, New York.

[17] T.Erdey-Gruz, Kinetics of Electrode Processes, in Wiley Interscience. 1972, John Wi- ley & Sons Inc, New York.

[18] Burgan, B.A., S.C. Institute, and S.S.A. Centre, Concise Guide to the Structural De- sign of Stainless Steel. 1993: Steel Construction Institute.

[19] International, A.S.M., A.S.M International, Metals Handbook, . Ninth edition ed. Vol.

[20] 1987: Corrosion (ASM Handbook).

[21] Schmitt, G. and M. Horstemeier, Fundamental Aspects of CO2 Metal Loss Corrosion Part II: Influence of Different Parameters on CO2 Corrosion Mechanisms. 2006, NACE International.

[22] Charng, T.L., F., Review of corrosion causes and corrosion control in a technical fa- cility. 1982: United States.

[23] Dugstad, K.V.a.A., Film Covered Corrosion, Film Breakdown and Pitting Attack of Carbon Steels in Aqueous CO2 Environments. Corrosion Analysis Network, 1988: p. 1 - 18.

[24] corrosion in oil and gas production. J. S. Smart, III. CORROSION 90/10, NACE, Houston, TX. Per Copy$, 1990.

[25] S.Nesic, J.P.a., Erosion–Corrosion in Single- and Multiphase Flow. 2011, in Uhlig's Corrosion Handbook: John Wiley & Sons, Inc., Hoboken, NJ, USA. .

[26] Venkatesh, E.S., Erosion Damage in Oil and Gas Wells. Society of Petroleum Engi- neers.

[27] Schmitt, G.A., et al., Understanding Localized CO2 Corrosion of Carbon Steel from Physical Properties of Iron Carbonate Scales. NACE International.

[28] Lillard, R.S., et al., Using Local Electrochemical Impedance Spectroscopy to Exam- ine Coating Failure.

[29] Dugstad, A.L., L and Videm, K, Parametric study of CO2 corrosion of carbon steel

[30] NACE International, Houston, TX., 1995.

[31] Nesic, S., et al., Mechanistic Modeling for CO2 Corrosion with Protective Iron Car- bonate Films. NACE International.

[32] Sontvedt, E.E.a.T., Effect of Flow on CO2 Corrosion Rate in Real and Synthetic For- mation Waters. Corrosion Analysis Network, 1983: p. 1-40.

[33] Waard, C.d., U. Lotz, and D.E. Milliams, Predictive Model for CO2 Corrosion Engi- neering in Wet Natural Gas Pipelines. CORROSION, 1991. 47(12): p. 976-985.

[34] WAARD, C.D. and D.E. MILLIAMS, Carbonic Acid Corrosion of Steel. CORRO- SION, 1975. 31(5): p. 177-181.

[35] Halvorsen, A.M. and T. Sontvedt, CO2 Corrosion Model for Carbon Steel Including Wall Shear Stress Model for Multiphase Flow and Limits for Production Rate to Avoid Mesa Attack. NACE International.

[36] STANDARD, N., CO2 corrosion rate calculation model. 2005.

[37] Garsany, Y., D. Pletcher, and B.M. Hedges, The Role of Acetate in CO2 Corrosion of Carbon Steel: Has the Chemistry Been Forgotten? NACE Inter

@article{1717141,
      author = {Lesor Ikeh},
      title = {X-Ray Photoelectron Spectroscopy (XPS) Spectra Characterization of Mild Steel Corrosion in Carbon Dioxide (CO2) Deaerated Environment.},
      journal = {Iconic Research And Engineering Journals},
      year = {2026},
      volume = {9},
      number = {10},
      pages = {3966-3974},
      issn = {2456-8880},
      url = {https://www.irejournals.com/formatedpaper/1717141.pdf},
      abstract = {Corrosion of pipeline remain a major challenge in the oil and gas industry. Corrosion in oil and gas pipelines is an electrochemical process causing significant material degradation, leading to leaks, ruptures, and, on average, 50%–70% of pipeline failures. It is driven by environmental factors or contaminants such as CO2, H2S and water. Internal corrosion slows or decreases the production of oil and gas when associated with free water and reacts with organic acid. The aim of this study is to characterize the corrosion of carbon steel and surface film composition in well deaerated environment (3.5 wt. % Nacl) using the X-Ray Photoelectron Spectroscopy (XPS). The XPS characterization focused on identifying the chemical states of Fe, O, and C on the surface, revealing that corrosion products were primarily composed of a FeCO3 film, with traces of iron oxides (FeO), or (FeOOH). The results shows that the XPS analyses on the samples reviewed some of the elements are absence on addition of HAc to the solution. The Fe 2p spectra shows peaks corresponding to metallic iron, (FeO) from the substrate and Fe2+ and Fe3+ states from the corrosion products with Fe2+ in FeCO3 being dorminant in the passive film. Similarly, A prominent peak at approximately 290.5 eV, characteristic of the carbonate ion, CO32- in FeCO3 confirmed the formation of iron carbonate.The oxygen spectra were deconvoluted into multiple states, highlighting the presence of O2- and CO32-},
      keywords = {X-Ray, Spectra, Carbon Steel, Corrosion, Environment, Spectroscopy, Photoelectron.},
      month = {April},
      doi = {https://doi.org/10.64388/IREV9I10-1717141}
  }